Structural, electrochemical and photophysical investigations of Re(I)-complexes of κ(3)N-tridentate heterocyclic ligands.
نویسندگان
چکیده
fac,fac-[Re(I)(CO)3]-complexes of new κ(3)N-tridentate ligands were synthesized and characterized by various analytical techniques including XRD. The regulation of electronic properties of the complexes upon ligand modification is discussed.
منابع مشابه
Synthesis of discrete Re(I) di- and tricarbonyl assemblies using a [4 × 1] directional bonding strategy.
Discrete self-assembly of two Re(I) squares was achieved by a simple and efficient strategy where the complexes, [Re(4-pytpy-κ(2)N)(CO)3Br] and [Re(4-pytpy-κ(3)N)(CO)2Br], act as their own ligands. The photophysical and electrochemical properties of the assemblies and their precursors are described along with solid-state X-ray diffraction studies.
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عنوان ژورنال:
- Dalton transactions
دوره 43 31 شماره
صفحات -
تاریخ انتشار 2014